The Casimir--Polder interaction between an anisotropic particle and a surface is orientation dependent. We study novel orientational effects that arise due to curvature of the surface for distances much smaller than the radii of curvature by employing a derivative expansion. For nanoparticles we derive a general short distance expansion of the interaction potential in terms of their dipolar polarizabilities. Explicit results are presented for nano-spheroids made of SiO2 and gold, both at zero and at finite temperatures. The preferred orientation of the particle is strongly dependent on curvature, temperature, as well as material properties.